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Lifetime enhancement for multi-photon absorption in intermediate band solar cells

机译:中频带多光子吸收的寿命增强   太阳能电池

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摘要

A semiconductor structure consisting of two coupled quantum wells embeddedinto the intrinsic region of a {\it p-i-n} junction is proposed to beimplemented as an intermediate band solar cell with ratchet state. Thelocalized conduction subband of the right-hand side quantum well is thought asthe intermediated band, while the excited conduction subband of the right-handside quantum well, coupled to right-rand side one, is thought to acts as theratchet state. The photo-excited electron in the intermediate band can tunnelout the thin barrier separating the wells and accumulate into ratchet subband.This might raise the electron probability of being hit by a second photon andexiting out to the continuum, increasing solar cell current. Is presented atemporal rate model for describing the charge transport properties of the cell.Calculations are carried out by solving the time-dependent Schr\"odingerequation applying the time evolution operator within a pertinent choice of thenon-commuting kinetic and potential operators. The efficiency in the generationof current is analyzed directly by studying the occupation of the subbandswells in the p-i-n junction, taking into account the injection and drainingdynamic provided by the electrical contacts connected to the cell. As a result,the efficiency in the generation of current was found to be directly correlatedto the relationship between optical generation and recombination ratesregarding to the scattering to the ratchet state rate. This suggests that agood coupling between the intermediate band and the additional band is a keypoint to be analyzed when developing an efficient solar cell.
机译:提出了一种由两个嵌入量子结的本征区的耦合量子阱组成的半导体结构,以实现具有棘轮状态的中带太阳能电池。右侧量子阱的局部传导子带被认为是中间带,而右侧量子阱的被激发的传导子带被耦合到棘齿状的一阶。中间带中的光激发电子可以隧穿分隔阱的薄壁垒并积累到棘轮子带中,这可能会增加电子被第二个光子击中并出射到连续体的可能性,从而增加了太阳能电池电流。提出了一种描述电池电荷传输特性的时空速率模型。通过在非换向动力学和势能算子的相关选择中应用时间演化算子来求解时间相关的薛定od方程,从而进行计算。考虑到连接到电池的电触点所提供的注入和排放动力学,通过研究销结中子带的占有率直接分析了电流的产生,结果发现电流产生的效率为散射与棘轮态速率之间的关系与光的产生与复合速率之间的关系直接相关,这表明在开发高效太阳能电池时,要充分分析中间带与附加带之间的良好耦合。

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